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Электрохимия, 2023, T. 59, № 10, стр. 579-592

Универсальная электрокаталитическая система для превращения спиртов в карбонильные соединения и функциональные производные карбоновых кислот

В. П. Кашпарова a, *, Е. Н. Шубина a, b, Д. В. Токарев a, Г. П. Антропов b, И. Ю. Жукова b, **

a Южно-Российский государственный политехнический университет (НПИ) им. М.И. Платова
346428 Новочеркасск, ул. Просвещения, 132, Россия

b Донской государственный технический университет
344000 Ростов-на-Дону, пл. Гагарина, 1, Россия

* E-mail: kashparova2013@mail.ru
** E-mail: iyuzh@mail.ru

Поступила в редакцию 18.01.2023
После доработки 16.02.2023
Принята к публикации 19.02.2023

Аннотация

Разработана универсальная каталитическая система 4-ацетамидо-2,2,6,6-тетраметилпиперидин-1-оксил/KI/пиридиновое основание для непрямого электроокисления спиртов в карбонильные соединения и производные карбоновых кислот. Использование пиридина, 2,6-лутидина или коллидина позволило получить карбонильные соединения (выход до 100%) после пропускания 2–2.2 F. В присутствии пиридина спирты жирного и жирно-ароматического рядов превращены в симметричные сложные эфиры (выход до 35%) после пропускания 4 F. Ангидриды кислот (выход до 80%) образуются при использовании 2,6-лутидина или коллидина после пропускания 5–6 F. В присутствии 2,6-лутидина и источника азота получены нитрилы (выход до 99%) после пропускания 4–4.5 F.

Ключевые слова: электрокаталитическая система, пиридиновые основания, спирты, карбонильные соединения, сложные эфиры, ангидриды, нитрилы

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