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Электрохимия, 2023, T. 59, № 12, стр. 753-789

Реакционная способность анион-радикалов и дианионов органических соединений (обзор)

А. С. Мендкович a, *, А. И. Русаков b

a Институт органической химии им. Н.Д. Зелинского РАН
Москва, Россия

b Ярославский государственный университет им. П.Г. Демидова
Ярославль, Россия

* E-mail: asm@free.net

Поступила в редакцию 07.11.2022
После доработки 12.03.2023
Принята к публикации 28.03.2023

Аннотация

Проанализированы результаты экспериментальных и теоретических исследований реакций с участием π*-анион-радикалов и π*-дианионов. На примере трех, наиболее характерных для них, реакций рассмотрены основные факторы, определяющие реакционную способность этих частиц.

Ключевые слова: анион-радикалы, дианионы, электровосстановление, перенос электрона, квантово-химические расчеты, димеризация, протонирование, разрыв связи

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