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Электрохимия, 2023, T. 59, № 11, стр. 716-725

Электрохимическое фосфорилирование терминальных ацетиленов

М. В. Тарасов a, *, В. В. Хризанфорова a, Т. В. Грязнова a, Ю. Г. Будникова a

a Институт органической и физической химии им. А.Е. Арбузова, ФИЦ Казанский научный центр
Казань, Россия

* E-mail: t.maxim1618@gmail.com

Поступила в редакцию 29.11.2022
После доработки 15.03.2023
Принята к публикации 21.03.2023

Аннотация

Электрокаталитическое фосфорилирование терминальных ацетиленов диарилфосфиноксидами в присутствии катализатора bpyCo(BF4)2 впервые реализовано в условиях электровосстановления с выходами целевых продуктов до 75%. Природа растворителя и фонового электролита, присутствие кислорода и воды определяют образование насыщенных и ненасыщенных продуктов фосфорилирования ацетиленов. Варьирование вышеописанных факторов осуществлялось с целью оптимизации процесса электросинтеза для достижения стерео- и хемоселективности. Вольтамперометрические исследования использовали для установления редокс-свойств реагентов для понимания процессов с участием кобальтового катализатора.

Ключевые слова: терминальный ацетилен, диарилфосфиноксид, кобальтовый катализатор, электролиз, электрохимическое восстановление, циклическая вольтамперометрия

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